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MSi2H2+ structure (M: Cr, Mn and W) theoretical and FT-IRC mass spectrometry study

EuroSciCon Conference on Biochemical, Chemical Engineering & Mass Spectrometry
November 19-20, 2018 Prague, Czech Republic

A Ferhati

LCCE-Universite de Batna, Algerie

Posters & Accepted Abstracts: Arch Chem


Progress has been made in the knowledge of the nature of the M-X bonding (M=Cr, Mn and W; X=C, Si…) both experimentally and theoretically. A Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) study of the gas phase reaction I of M+ with SiH4 is reported here in order to give more insight on the structure of the MSi2H2+ ion M++ 2SiH4—>MSi2H2 ++2H2 (I) The structure of the MSi2H2+ ions are discussed in terms of CID result confronted to the theoretical calculation at the DFT level on the different structural geometries.

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